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减缩型聚羧酸减水剂的合成研究

作者:林艳梅,张小芳,史艳娜

关键字:减缩型,聚,羧酸,减,水剂,的,合成,研究,科之,

 
(科之杰新材料集团有限公司,福建 厦门  361101)
    摘要:将丙烯酸与一缩二丙二醇酯化得到的减缩功能单体P,再与丙烯酸、异戊烯醇聚氧乙烯醚(TPEG)共聚制得减缩型聚羧酸减水剂(PCE1)。研究了普通型聚羧酸减水剂(Point-MS)及合成的PCE1对水泥基材料收缩性能和混凝土收缩性能的影响。结果表明,合成减缩型聚羧酸减水剂PCE1的综合性能优异,具有分散性能佳、保坍能力强和减缩等功能。
    关键词:减缩;聚羧酸减水剂;合成研究
    中图分类号:TU528.042+.2        文献标识码:A        文章编号:1001-702X(2020)12-0145-03
 
Synthetic research of shrinkage reducing polycarboxylate superplasticizer
LIN Yanmei,ZHANG Xiaofang,SHI Yanna 
(KZJ New Materials Group Co. Ltd.,Xiamen 361101,China)
    Abstract:Shrinkage reducing polycarboxylate superplasticizer was synthesized with acrylic acid,isopentenol polyoxyethylene ether(TPEG) and shrinkage-reducing monomer P. Monomer P obtained by esterification of acrylic acid with dipropylene glycol. The effects of ordinary polycarboxylate superplasticizer(Point-MS) and the synthetic shrinkage-reducing polycarboxylate superplasticizer(PCE1) on the shrinkage properties of cement-based materials and concrete were studied. The research shows that the synthetic shrinkage-reducing polycarboxylate superplasticizer has excellent comprehensive properties,good dispersing performance,strong slump retention,and shrinkage reduction.
    Key words:shrinkage reducing,polycarboxylate superplasticizer,synthesis research